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A novel polynorbornene-based chemosensor for the fluorescence sensing of Zn and Cd and subsequent detection of pyrophosphate in aqueous solutions

Dalton Transactions, ISSN: 1477-9234, Vol: 44, Issue: 16, Page: 7470-7476
2015
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Article Description

A hydroxyquinoline functionlized polynorbornene (P1) was designed and synthesized. In an aqueous solution, P1 shows a "turn-on" fluorescence response for Zn and Cd with a 50 nm blue shift. Furthermore, both P1-Zn and P1-Cd complexes were found to respond to pyrophosphate (PPi) over other important biological anions via a fluorescence quenching effect. P1 is also capable of monitoring intracellular Zn and PPi in real time.

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