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Copper-catalyzed cyanation of aryl iodides with α-cyanoacetates via C-CN bond activation

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 13, Issue: 39, Page: 9963-9968
2015
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Article Description

A Cu(i)-catalyzed cyanation reaction of aryl iodides with α-cyanoacetates is reported herein, which uses α-cyanoacetates as the nontoxic and easy-handling CN source through copper-mediated C-CN bond cleavage. This reaction enables access to aryl nitriles with an array of functional groups on the aromatic ring in good to excellent yields.

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