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Toward a tunable synthetic [FeFe] hydrogenase mimic: Single-chain nanoparticles functionalized with a single diiron cluster

Polymer Chemistry, ISSN: 1759-9962, Vol: 6, Issue: 44, Page: 7646-7651
2015
  • 63
    Citations
  • 0
    Usage
  • 63
    Captures
  • 0
    Mentions
  • 19
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    63
    • Citation Indexes
      63
  • Captures
    63
  • Social Media
    19
    • Shares, Likes & Comments
      19
      • Facebook
        19

Article Description

We report two novel "clickable" [(μ-SCHNR)Fe(CO)] complexes and their incorporation into single-chain nanoparticles. Variations in the characteristic iron-carbonyl stretching bands caused by the polymer scaffolds confirmed changes in the symmetry and electronics of the complexes. This represents the first SCNP-based model of a metalloenzyme bearing a single, bioinspired active site.

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