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Online quantitative mass spectrometry for the rapid adaptive optimisation of automated flow reactors

Reaction Chemistry and Engineering, ISSN: 2058-9883, Vol: 1, Issue: 1, Page: 96-100
2016
  • 109
    Citations
  • 0
    Usage
  • 133
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    109
    • Citation Indexes
      109
  • Captures
    133

Article Description

An automated continuous reactor for the synthesis of organic compounds, which uses online mass spectrometry (MS) for reaction monitoring and product quantification, is presented. Quantitative and rapid MS monitoring was developed and calibrated using HPLC. The amidation of methyl nicotinate with aqueous MeNH2 was optimised using design of experiments and a self-optimisation algorithm approach to produce >93% yield.

Bibliographic Details

Holmes, Nicholas; Akien, Geoffrey R.; Savage, Robert J. D.; Stanetty, Christian; Baxendale, Ian R.; Blacker, A. John; Taylor, Brian A.; Woodward, Robert L.; Meadows, Rebecca E.; Bourne, Richard A.

Royal Society of Chemistry (RSC)

Chemical Engineering; Chemistry

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