Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments
Chemical Science, ISSN: 2041-6539, Vol: 6, Issue: 5, Page: 2989-2996
2015
- 18Citations
- 22Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations18
- Citation Indexes18
- CrossRef18
- 17
- Captures22
- Readers22
- 22
Article Description
The M-(η2-BMn) complex [(η5-C5H5)(OC)2Mn{μ-B(Cl)(tBu)Au(PPh3)}] (2) can be functionalized via halide substitution reactions to afford isostructural complexes [(η5-C5H5)(OC)2Mn{μ-B(R)(tBu)Au(PPh3)}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh3)] (M = Au, Ag and Cu) in the presence of halide abstraction reagents to afford borylene-bridged heteromultinuclear complexes [{(η5-C5H5)(OC)2Mn}2{μ2-B(tBu)}2M][BAr4x] (M = Au, Ag and Cu; Arx = 3,5-C6H3Cl2, 3,5-C6H3(CF3)2). Experimental characterization as well as computational studies revealed that these complexes are best viewed as transition metal borylene complexes side-on coordinated to monovalent coinage metal cations, thus representing the first boron analogs of Stone's alkylidyne-bridged multinuclear complexes.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84928138343&origin=inward; http://dx.doi.org/10.1039/c5sc00211g; http://www.ncbi.nlm.nih.gov/pubmed/29403636; http://xlink.rsc.org/?DOI=C5SC00211G; http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00211G; https://xlink.rsc.org/?DOI=C5SC00211G; https://dx.doi.org/10.1039/c5sc00211g; https://pubs.rsc.org/en/content/articlelanding/2015/sc/c5sc00211g
Royal Society of Chemistry (RSC)
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