Effects of reagent rotation on interferences in the product angular distributions of chemical reactions
Chemical Science, ISSN: 2041-6539, Vol: 7, Issue: 1, Page: 642-649
2016
- 20Citations
- 9Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations20
- Citation Indexes20
- 20
- CrossRef19
- Captures9
- Readers9
Article Description
Differential cross sections (DSCs) of the HD(v′, j′) product for the reaction of H atoms with supersonically cooled D molecules in a small number of initial rotational states have been measured at a collision energy of 1.97 eV. These DCSs show an oscillatory pattern that results from interferences caused by different dynamical scattering mechanisms leading to products scattered into the same solid angle. The interferences depend on the initial rotational state j of the D (v = 0, j) reagent and diminish in strength with increasing rotation. We present here a detailed explanation for this behavior and how each dynamical scattering mechanism has a dependence on the helicity Ω, the projection of the initial rotational angular momentum j of the D reagent on the approach direction. Each helicity corresponds to a different internuclear axis distribution, with the consequence that the dependence on Ω reveals the preference of the different quasiclassical mechanisms as a function of approach direction. We believe that these results are general and will appear in any reaction for which several mechanisms are operative.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84950316970&origin=inward; http://dx.doi.org/10.1039/c5sc03373j; http://www.ncbi.nlm.nih.gov/pubmed/28791109; https://xlink.rsc.org/?DOI=C5SC03373J; http://xlink.rsc.org/?DOI=C5SC03373J; http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03373J; https://dx.doi.org/10.1039/c5sc03373j; https://pubs.rsc.org/en/content/articlelanding/2016/sc/c5sc03373j
Royal Society of Chemistry (RSC)
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