Single-chain polybutadiene organometallic nanoparticles: An experimental and theoretical study
Chemical Science, ISSN: 2041-6539, Vol: 7, Issue: 3, Page: 1773-1778
2016
- 29Citations
- 27Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations29
- Citation Indexes29
- CrossRef29
- 29
- Captures27
- Readers27
- 27
Article Description
High molecular weight polybutadienes and rhodium complexes were used to produce single chain organometallic nanoparticles. Irradiation of high cis-polybutadiene in the presence of a photosensitizer isomerised the double bonds to produce differing cis/trans ratios within the polymer. Notably, a higher cis percentage of carbon-carbon double bonds within the polymer structure led to faster binding of metal ions, as well as their faster removal by competing phosphine ligands. The experimental results were supported and rationalized by DFT computations.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84959367069&origin=inward; http://dx.doi.org/10.1039/c5sc04535e; http://www.ncbi.nlm.nih.gov/pubmed/28936327; https://xlink.rsc.org/?DOI=C5SC04535E; http://xlink.rsc.org/?DOI=C5SC04535E; http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04535E; https://dx.doi.org/10.1039/c5sc04535e; https://pubs.rsc.org/en/content/articlelanding/2016/sc/c5sc04535e
Royal Society of Chemistry (RSC)
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