An elusive vinyl radical isolated as an appended unit in a five-coordinate Co(III)-bis(iminobenzosemiquinone) complex formed: Via ligand-centered C-S bond cleavage
Chemical Communications, ISSN: 1364-548X, Vol: 52, Issue: 70, Page: 10613-10616
2016
- 18Citations
- 9Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Redox-active ligand HPra experienced C-S bond cleavage during complexation reaction with Co(OAc)·2HO in the presence of EtN in CHOH in air. Thus, formed complex 1 was composed of two iminobenzosemiquinone radicals in its coordination sphere and an unprecedented stable tethered-vinyl radical. The complex has been characterized by mass, X-ray single crystal, X-band EPR, variable-temperature magnetic moment measurements and DFT based computational study.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84983607538&origin=inward; http://dx.doi.org/10.1039/c6cc02751b; http://www.ncbi.nlm.nih.gov/pubmed/27439588; https://xlink.rsc.org/?DOI=C6CC02751B; http://xlink.rsc.org/?DOI=C6CC02751B; http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC02751B; https://dx.doi.org/10.1039/c6cc02751b; https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc02751b
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know