Pd-Catalyzed C(sp)-H carbonylation of 2-benzylpyridines for the synthesis of pyridoisoquinolinones
Chemical Communications, ISSN: 1364-548X, Vol: 52, Issue: 87, Page: 12873-12876
2016
- 25Citations
- 12Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations25
- Citation Indexes25
- 25
- CrossRef22
- Captures12
- Readers12
- 12
Article Description
An efficient synthesis of pyridoisoquinolinones, through Pd-catalyzed carbonylative annulation of 2-benzylpyridines, has been developed. The pyridinyl moiety in the substrate acts as both a directing group and an internal nucleophile for sp C-H activation and pyridocarbonylation. The ready availability of 2-benzylpyridines as well as the operational practicality makes this transformation potentially useful for the synthesis of analogues of protoberberine alkaloids.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84992709837&origin=inward; http://dx.doi.org/10.1039/c6cc07612b; http://www.ncbi.nlm.nih.gov/pubmed/27738677; https://xlink.rsc.org/?DOI=C6CC07612B; http://xlink.rsc.org/?DOI=C6CC07612B; http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC07612B; https://dx.doi.org/10.1039/c6cc07612b; https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc07612b
Royal Society of Chemistry (RSC)
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