Synthesis of oxindole from acetanilide via Ir(iii)-catalyzed C-H carbenoid functionalization
Chemical Communications, ISSN: 1364-548X, Vol: 53, Issue: 2, Page: 443-446
2017
- 58Citations
- 25Captures
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Metrics Details
- Citations58
- Citation Indexes58
- 58
- CrossRef49
- Captures25
- Readers25
- 25
Article Description
Herein we disclose the first report on the synthesis of oxindole derivatives from acetanilide via Ir(iii)-catalyzed intermolecular C-H functionalization with diazotized Meldrum's acid. A broad range of substituted anilides were found to react smoothly under the Ir(iii)-catalytic system to afford the corresponding N-protected oxindoles. The N-protecting groups, such as Ac, Bz or Piv, can be easily removed to furnish the oxindole. Various synthetic applications of the synthesized oxindole were also demonstrated.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85007494864&origin=inward; http://dx.doi.org/10.1039/c6cc08788d; http://www.ncbi.nlm.nih.gov/pubmed/27966703; https://xlink.rsc.org/?DOI=C6CC08788D; http://xlink.rsc.org/?DOI=C6CC08788D; http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC08788D; https://dx.doi.org/10.1039/c6cc08788d; https://pubs.rsc.org/en/content/articlelanding/2017/cc/c6cc08788d
Royal Society of Chemistry (RSC)
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