PlumX Metrics
Embed PlumX Metrics

Tuning the electronic structure of thiolate-protected 25-atom clusters by co-substitution with metals having different preferential sites

Dalton Transactions, ISSN: 1477-9234, Vol: 45, Issue: 45, Page: 18064-18068
2016
  • 49
    Citations
  • 0
    Usage
  • 28
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

Article Description

Trimetallic AuAgPd and tetrametallic AuAgCuPd clusters were synthesized by the subsequential metal exchange reactions of dodecanethiolate-protected AuPd clusters. EXAFS measurements revealed that Pd, Ag, and Cu dopants preferentially occupy the center and edge sites of the core, and staple sites, respectively. Spectroscopic and theoretical studies demonstrated that the synergistic effects of multiple substitutions on the electronic structures are additive in nature.

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know