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Selective complexation of di-: N -hexylammonium salts by tailed porphyrin host

New Journal of Chemistry, ISSN: 1369-9261, Vol: 40, Issue: 7, Page: 5679-5682
2016
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    3
    • Citation Indexes
      3

Article Description

Novel types of tailed porphyrins have been synthesized and characterized. The tail was coordinated intramolecularly to zinc porphyrin, leading to the formation of a cavity. In the cavity, tailed porphyrins formed a complex with di-n-hexylammonium salts. The binding affinities of the tailed porphyrins were studied by H NMR and UV-visible titration experiments. The selectivity of complexation was attributed to the induced fit and lipophilic interactions.

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