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Switching between intermolecular and intramolecular reactions using flow microreactors: Lithiation of 2-bromo-2′-silylbiphenyls

Organic Chemistry Frontiers, ISSN: 2052-4129, Vol: 3, Issue: 10, Page: 1250-1253
2016
  • 7
    Citations
  • 0
    Usage
  • 13
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    7
    • Citation Indexes
      7
  • Captures
    13

Article Description

Reaction-pathway control of 2-lithio-2′-silylbiphenyls was accomplished in flow microreactor systems. Effective switching between the intermolecular reaction with an electrophile and the intramolecular reaction was performed at will by choosing an appropriate residence time and temperature region.

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