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Gold/gallium-catalyzed annulation of 1,3-dicarbonyl compounds and cyclopropylacetylenes for synthesis of substituted cyclopentenes

RSC Advances, ISSN: 2046-2069, Vol: 6, Issue: 21, Page: 17386-17389
2016
  • 10
    Citations
  • 0
    Usage
  • 11
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    10
    • Citation Indexes
      10
  • Captures
    11

Article Description

An efficient synthesis of substituted cyclopentenes through gold/gallium-catalyzed annulation of 1,3-dicarbonyl compounds and cyclopropylacetylenes is achieved. This tandem reaction consists of a gold-catalyzed Nakamura reaction, a catalytic dienol-enone tautomerization, and a gallium-catalyzed vinylcyclopropane (VCP) rearrangement.

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