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Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry

RSC Advances, ISSN: 2046-2069, Vol: 6, Issue: 107, Page: 105801-105805
2016
  • 52
    Citations
  • 0
    Usage
  • 54
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    52
    • Citation Indexes
      52
  • Captures
    54

Article Description

A combination of UV-Vis and resonance Raman spectroscopy in conjunction with electrochemistry is employed to reveal the nature of a side product formed when using heteroleptic Cu(i)-photosensitizers [(P^P)Cu(N^N)] for photocatalytic hydrogen generation. It is shown that homoleptic [Cu(N^N)] complexes are formed under oxidative conditions confirming a proposed deactivation pathway.

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