Experimental and theoretical evaluation of structures of Pr@C and its functionalized adduct with adamantylidene carbene
RSC Advances, ISSN: 2046-2069, Vol: 6, Issue: 116, Page: 115113-115119
2016
- 6Citations
- 4Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
In this study, we prepared and isolated the pristine endohedral dimetallofullerene Pr@C, whose structure was determined to be Pr@D(10611)-C by a combination of mass spectrometry, UV-visible-near-infrared absorption spectroscopy, and quantum mechanics characterization. Furthermore, we explored the reactivity of Pr@D(10611)-C using its functionalization by 2-adamantane-2,3-[3H]-diazirine, and the resulting adducts were identified by mass spectrometry and high performance liquid chromatography. Additionally, the preferred addition positions and isomeric structures of the dominant mono-adduct Pr@C(Ad) were further investigated using density functional theory.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85006380946&origin=inward; http://dx.doi.org/10.1039/c6ra23224h; https://xlink.rsc.org/?DOI=C6RA23224H; http://xlink.rsc.org/?DOI=C6RA23224H; http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA23224H; https://dx.doi.org/10.1039/c6ra23224h; https://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra23224h
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know