Silsesquioxane cages as fluoride sensors
Chemical Communications, ISSN: 1364-548X, Vol: 53, Issue: 89, Page: 12108-12111
2017
- 68Citations
- 45Captures
- 2Mentions
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations68
- Citation Indexes68
- 68
- CrossRef61
- Captures45
- Readers45
- 45
- Mentions2
- References2
- Wikipedia2
Article Description
Pyrene functionalized silsesquioxane cages (PySQ) not only provide significant fluorescence from pyrene-pyrene excimers with a very large Stokes shift (Δλ = 143 nm, 69 930 cm) in DMSO but also exhibit fluoride capture results coincidentally with a π-π∗ fluorescence enhancement. On the other hand, PySQ-F in THF significantly exhibits π-π∗ fluorescence quenching and a color change can be observed with the naked eye from light yellow to deep orange by forming a charge-transfer (CT) complex among the pyrenyl rings. Moreover, PySQ selectively captures F with a response time of <2 min and with a very low detection limit (1.61 ppb), while F NMR is used to confirm encapsulation of F with Δδ = 19 ppm.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85033229177&origin=inward; http://dx.doi.org/10.1039/c7cc06647c; http://www.ncbi.nlm.nih.gov/pubmed/29072723; https://xlink.rsc.org/?DOI=C7CC06647C; http://xlink.rsc.org/?DOI=C7CC06647C; http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC06647C; https://dx.doi.org/10.1039/c7cc06647c; https://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc06647c
Royal Society of Chemistry (RSC)
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