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Th(IV) and Ce(IV) napthylsalophen sandwich complexes: Characterization of unusual thorium fluorescence in solution and solid-state

Chemical Communications, ISSN: 1364-548X, Vol: 53, Issue: 88, Page: 11984-11987
2017
  • 25
    Citations
  • 0
    Usage
  • 14
    Captures
  • 1
    Mentions
  • 1
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    25
  • Captures
    14
  • Mentions
    1
    • Blog Mentions
      1
      • Blog
        1
  • Social Media
    1
    • Shares, Likes & Comments
      1
      • Facebook
        1

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Th(IV) and Ce(IV) Napthylsalophen Sandwich Complexes: Characterization of Unusual Thorium Fluorescence in Solution and Solid-state

Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC06868A, Communication Emily Elizabeth Hardy, Kevin M Wyss, John D Gorden, Isuru R Ariyarathna, Evangelos Miliordos, Anne E. V.

Article Description

The synthesis, characterization, and electronic spectroscopy of two ML sandwich complexes, where M = Ce(iv) or Th(iv) and L = napthylsalophen are described. The ThL complex, unlike the isovalent CeL, complex possesses unusual fluorescence properties in both solution and solid-state. These observations are explained with TD-DFT.

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