Chiral supramolecular organization from a sheet-like achiral gel: A study of chiral photoinduction
Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 19, Issue: 21, Page: 13622-13628
2017
- 6Citations
- 13Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations6
- Citation Indexes6
- CrossRef5
- Captures13
- Readers13
- 13
Article Description
Chiral photoinduction in a photoresponsive gel based on an achiral 2D architecture with high geometric anisotropy and low roughness has been investigated. Circularly polarized light (CPL) was used as a chiral source and an azobenzene chromophore was employed as a chiral trigger. The chiral photoinduction was studied by evaluating the preferential excitation of enantiomeric conformers of the azobenzene units. Crystallographic data and density functional theory (DFT) calculations show how chirality is transferred to the achiral azomaterials as a result of the combination of chiral photochemistry and supramolecular interactions. This procedure could be applied to predict and estimate chirality transfer from a chiral physical source to a supramolecular organization using different light-responsive units.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85024406021&origin=inward; http://dx.doi.org/10.1039/c7cp01739a; http://www.ncbi.nlm.nih.gov/pubmed/28524194; https://xlink.rsc.org/?DOI=C7CP01739A; http://xlink.rsc.org/?DOI=C7CP01739A; http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01739A; https://dx.doi.org/10.1039/c7cp01739a; https://pubs.rsc.org/en/content/articlelanding/2017/cp/c7cp01739a
Royal Society of Chemistry (RSC)
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