Hydrogen assisted synthesis of branched nickel nanostructures: A combined theoretical and experimental study
Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 19, Issue: 39, Page: 26718-26727
2017
- 12Citations
- 20Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations12
- Citation Indexes12
- CrossRef12
- 12
- Captures20
- Readers20
- 20
Article Description
The selective adsorption of small molecules over specific facets plays an important role in morphology controlled synthesis of metal nanocrystals. In the present work, hydrogen is found to be a good capping agent for direct synthesis of branched nickel nanocrystals, i.e., secondary branching (Ni-SB) nanoparticles and multipods (Ni-MP). Using ab initio thermodynamics and the Wulff construction principle, it has been found that: (i) in the presence of hydrogen (P = 6 bar), the facet structure stability follows the order of Ni(100) > Ni(111) > Ni(110), resulting in competitive over-growth along the 〈111〉 and 〈110〉 directions; (ii) with increasing hydrogen pressure, the Ni deposition rate over the crystal surface increases as a result of more Ni reduction; the competition between deposition and surface diffusion, therefore, becomes the vital factor for the nanocrystal growth process; (iii) the diffusion energy barrier of a surface Ni atom on Ni(111) is lower than that on Ni(110), especially on hydrogen covered surfaces, indicating that the kinetic over-growth only along the 〈111〉 direction producing Ni-MP will be dominant under P = 14 bar; (iv) the ab initio based Wulff construction principle predicts the shapes and morphologies at different hydrogen pressures which is further confirmed with HRTEM results. Finally, compared with nickel nanoparticles (Ni-NP) synthesized in the absence of hydrogen, the hydrogen assisted branched Ni nanomaterials, especially the Ni-MP, show higher catalytic activities for hydrogenation reactions of acetophenone and nitrobenzene.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85031326948&origin=inward; http://dx.doi.org/10.1039/c7cp04673a; http://www.ncbi.nlm.nih.gov/pubmed/28948245; http://xlink.rsc.org/?DOI=C7CP04673A; http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP04673A; https://xlink.rsc.org/?DOI=C7CP04673A; https://dx.doi.org/10.1039/c7cp04673a; https://pubs.rsc.org/en/content/articlelanding/2017/cp/c7cp04673a
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know