In situ synthesized 3D metal-organic frameworks (MOFs) constructed from transition metal cations and tetrazole derivatives: A family of insensitive energetic materials
Dalton Transactions, ISSN: 1477-9234, Vol: 46, Issue: 33, Page: 11046-11052
2017
- 54Citations
- 20Captures
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Metrics Details
- Citations54
- Citation Indexes53
- 53
- CrossRef52
- Patent Family Citations1
- Patent Families1
- Captures20
- Readers20
- 20
Article Description
The combination of the hydrothermal method with in situ synthesis has been successfully employed to prepare a family of tetrazole-based energetic metal-organic frameworks (EMOFs) ([Ag(Mtta)], 1; [Cd(Mtta)], 2; [Pb(bta)(O)(HO)], 3; and [Pb(tztr)(HO)], 4) through [2 + 3] cycloaddition of azide anions and nitrile groups. All the synthesized EMOFs were characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis (EA), different scanning calorimetry (DSC), and thermogravimetry (TG). Both complexes 1 and 4 consist of reticular two-dimensional (2D) layers that are linked by π-π overlap interactions between the ligands in neighbouring layers to form 3D supramolecular structures. In contrast, complexes 2 and 3 are 3D frameworks. The in situ formation of ligands bta and tztr has been described for the first time. Remarkably, thermogravimetric measurements demonstrated that the EMOFs 1-4 possess excellent thermostabilities with high decomposition temperatures up to 354, 389, and 372 °C for 1, 2, and 4, respectively. Sensitivity tests revealed that all the EMOFs are extremely insensitive.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85028076064&origin=inward; http://dx.doi.org/10.1039/c7dt02582c; http://www.ncbi.nlm.nih.gov/pubmed/28782787; https://xlink.rsc.org/?DOI=C7DT02582C; http://xlink.rsc.org/?DOI=C7DT02582C; http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02582C; https://dx.doi.org/10.1039/c7dt02582c; https://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt02582c
Royal Society of Chemistry (RSC)
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