Structural effects of trifluoromethylation and fluorination in gold(i) BIPHEP fluorothiolates
New Journal of Chemistry, ISSN: 1369-9261, Vol: 41, Issue: 19, Page: 10537-10541
2017
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- 9Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
We synthesised and characterised two new BIPHEP-bridged digold(i) perfluorothiolates. Experimental and theoretical analyses through the Quantum Theory of Atoms in Molecules revealed that the long-range inductive effects are larger for CF than they are for F. Moreover, the aurophilic interaction and F-Au contacts were qualified mostly as covalent and closed-shell type respectively.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85029941957&origin=inward; http://dx.doi.org/10.1039/c7nj02202f; http://xlink.rsc.org/?DOI=C7NJ02202F; http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ02202F; https://xlink.rsc.org/?DOI=C7NJ02202F; https://dx.doi.org/10.1039/c7nj02202f; https://pubs.rsc.org/en/content/articlelanding/2017/nj/c7nj02202f
Royal Society of Chemistry (RSC)
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