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Versatile "click" synthesis of 1-hydroxy-1,1-methylenebisphosphonic acids with thioalkoxy substituents for the preparation of stable gold nanoparticles

New Journal of Chemistry, ISSN: 1369-9261, Vol: 41, Issue: 20, Page: 12153-12158
2017
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Article Description

New structures of hydroxymethyl bisphosphonate (HMBP) were prepared through thiol-yne and thiol-ene click reactions. The synthesized polyethyleneglycol-functionalized HMBPs were then utilized for the one-pot synthesis of gold nanoparticles (Au NPs). These Au NPs were demonstrated to be highly stable in a physiological medium with high salt concentrations, and could moreover be efficiently functionalized by an organic dye leading to fluorescent Au NPs that are hours long stable in serum.

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