A new Zn(II) metal-organic framework having 3D CdSO topology as luminescent sensor and photocatalyst for degradation of organic dyes
New Journal of Chemistry, ISSN: 1369-9261, Vol: 42, Issue: 4, Page: 2767-2775
2018
- 88Citations
- 21Captures
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Article Description
A new Zn(ii) metal-organic framework, formulated as {[Zn(L)]·2.7 DMF} (1), was synthesized using a multidentate ligand 1,4-bis(triazol-1-yl)terephthalic acid (HL). The MOF 1 adopts 3D uninodal 4-c CdSO topology and behaves as a luminescent chemosensor for highly selective and sensitive detection of Fe and nitro-aromatics, particularly 2,4,6-trinitrophenol (TNP). In addition, the thermal stability, UV/Vis diffuse-reflection spectra and photocatalytic behaviors of 1 against organic dyes have also been investigated. The possible mechanism associated with the alleviation in the emission intensity of 1 in the presence of nitro-aromatic compounds were addressed by theoretical calculations. In addition, the photocatalytic activity of 1 against organic dyes was addressed using density of states (DOS) calculations.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85042019580&origin=inward; http://dx.doi.org/10.1039/c7nj04355d; https://xlink.rsc.org/?DOI=C7NJ04355D; http://pubs.rsc.org/en/Content/ArticleLanding/2018/NJ/C7NJ04355D; http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04355D; https://dx.doi.org/10.1039/c7nj04355d; https://pubs.rsc.org/en/content/articlelanding/2018/nj/c7nj04355d
Royal Society of Chemistry (RSC)
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