Syntheses, crystal structures, and photocatalytic properties of two ammonium-directed Ag-Sb-S complexes
Inorganic Chemistry Frontiers, ISSN: 2052-1553, Vol: 4, Issue: 6, Page: 954-959
2017
- 29Citations
- 8Captures
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Article Description
With ammonium ions as structure-directing agents, two novel silver thioantimonates (NH)AgSbS·HO (1) and (NH)AgSbS (2) have been surfactant-thermally synthesized and fully characterized. Compound 1 features a three dimensional (3D) open framework while compound 2 possesses a two dimensional (2D) layer structure. The optical band gaps are estimated to be 1.70 eV for 1 and 1.84 eV for 2, exhibiting semiconductor properties for visible light absorption. The photocatalytic experiments demonstrated that both 1 and 2 were able to degrade crystal violet (CV) and rhodamine B (RhB) under visible light irradiation. Moreover, compounds 1 and 2 also displayed selective photocatalytic abilities in CV degradation.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85021829778&origin=inward; http://dx.doi.org/10.1039/c7qi00130d; https://xlink.rsc.org/?DOI=C7QI00130D; http://xlink.rsc.org/?DOI=C7QI00130D; http://pubs.rsc.org/en/content/articlepdf/2017/QI/C7QI00130D; https://dx.doi.org/10.1039/c7qi00130d; https://pubs.rsc.org/en/content/articlelanding/2017/qi/c7qi00130d
Royal Society of Chemistry (RSC)
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