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Regio- and stereoselective syntheses of allylic thioethers under metal free conditions

RSC Advances, ISSN: 2046-2069, Vol: 7, Issue: 49, Page: 30594-30602
2017
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  • Citations
    19
    • Citation Indexes
      19
  • Social Media
    134
    • Shares, Likes & Comments
      134
      • Facebook
        134

Article Description

A metal free, regio and stereoselective syntheses of allylic thioethers using allyl iodides and aryl or alkyl disulfides as coupling partners is described. The densely functionalized allyl iodides having different stereochemistry (E & Z) reacted well with a variety of disulfides in a regio and stereoselective manner providing the resulting allyl aryl thioethers in 62-92% yields.

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