Imine-based [2]catenanes in water
Chemical Science, ISSN: 2041-6539, Vol: 9, Issue: 5, Page: 1317-1322
2018
- 46Citations
- 39Captures
- 1Mentions
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations46
- Citation Indexes46
- 46
- CrossRef44
- Captures39
- Readers39
- 39
- Mentions1
- References1
- 1
Article Description
We report the efficient condensation of imine-based macrocycles from dialdehyde A and aliphatic diamines B in pure water. Within the libraries, we identified a family of homologous amphiphilic [2]catenanes, whose self-assembly is primarily driven by the hydrophobic effect. The length and odd-even character of the diamine alkyl linker dictate both the yield and the conformation of the [2]catenanes, whose particular thermodynamic stability further shifts the overall equilibrium in favour of imine condensation. These findings highlight the role played by solvophobic effects in the self-assembly of complex architectures.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85041451443&origin=inward; http://dx.doi.org/10.1039/c7sc04901c; http://www.ncbi.nlm.nih.gov/pubmed/29675178; https://xlink.rsc.org/?DOI=C7SC04901C; http://xlink.rsc.org/?DOI=C7SC04901C; http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04901C; https://dx.doi.org/10.1039/c7sc04901c; https://pubs.rsc.org/en/content/articlelanding/2018/SC/C7SC04901C
Royal Society of Chemistry (RSC)
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