PlumX Metrics
Embed PlumX Metrics

A rhodium-catalyzed transannulation of N -(per)fluoroalkyl-1,2,3-triazoles under microwave conditions-a general route to N -(per)fluoroalkyl-substituted five-membered heterocycles

Chemical Communications, ISSN: 1364-548X, Vol: 54, Issue: 26, Page: 3258-3261
2018
  • 53
    Citations
  • 0
    Usage
  • 38
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

Article Description

A rhodium-catalyzed transannulation via ring-opening of N-(per)fluoroalkyl-substituted 1,2,3-triazoles followed by cycloaddition with different nitriles, enol ethers, isocyanates and silyl ketene acetals under microwave heating provided a highly efficient route to previously unreported N-(per)fluoroalkyl-substituted imidazoles, pyrroles, imidazolones and pyrrolones, respectively. These reactions were found to be applicable to the synthesis of a variety of 5-membered heterocycles bearing different (per)fluoroalkyl substituents as well as both electron-donating and electron-withdrawing groups attached to the heterocyclic core.

Bibliographic Details

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know