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Sensing the chirality of various organic solvents by helically arranged π-blades

Chemical Communications, ISSN: 1364-548X, Vol: 54, Issue: 87, Page: 12314-12317
2018
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Article Description

Although the chiral enrichment of dynamic prochiral molecules usually requires a strong interaction with a chiral source, the enantiomer ratio of a propeller-shaped molecule, obtained by a recently developed boron-mediated benzannulation reaction of alkynes, is biased in various organic solvents through solvation for the propeller moieties.

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