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Synthesis of chiral supramolecular bisphosphinite palladacycles through hydrogen transfer-promoted self-assembly process

Chemical Communications, ISSN: 1364-548X, Vol: 54, Issue: 72, Page: 10132-10135
2018
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Article Description

P-Chiral secondary phosphine oxides react with Pd(dba) in an acidic medium to provide chiral supramolecular bisphosphinite palladacycles through a H-transfer-based self-assembly process prior to SPO-promoted oxidative addition of an acid to a Pd(0) centre. The one-pot methodology allows variations of the X-type ligand as desired. Eight complexes have been characterised by X-ray diffraction.

Bibliographic Details

Vasseur, Alexandre; Membrat, Romain; Palpacelli, Davide; Giorgi, Michel; Nuel, Didier; Giordano, Laurent; Martinez, Alexandre

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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