PlumX Metrics
Embed PlumX Metrics

An organic-base catalyzed asymmetric 1,4-addition of tritylthiol to: In situ generated aza- o -quinone methides at the HO/DCM interface

Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 18, Page: 2668-2671
2019
  • 16
    Citations
  • 0
    Usage
  • 12
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

Article Description

Based on an efficient method for in situ generation of N-o-QM species in the presence of a base, enantioselective catalytic conjugated additions of tritylthiol to in situ generated N-o-QMs are reported. Acid-base bifunctional organocatalyst 4c (10 mol%) enables these transformations with high stereoselectivities (up to 94% ee) using HO/DCM as a solvent under mild conditions.

Bibliographic Details

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know