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Mid-infrared absorption of trapped electrons in titanium(IV) oxide particles using a photoacoustic FTIR technique

Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 20, Issue: 38, Page: 24519-24522
2018
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Mid-infrared absorption of titanium(iv) oxide (TiO) under ultraviolet (UV) irradiation was studied by Fourier transform infrared spectroscopy using a photoacoustic (PA) technique. UV irradiation induced an upward shift of the PA spectra, which is due to the trivalent titanium (Ti) species produced by electron accumulation. The PA spectra under UV irradiation mainly depend on the crystal structure, indicating that the energy levels of Ti are largely determined by crystal structures.

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