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Construction of CdS/MoS heterojunction from core-shell MoS @Cd-MOF for efficient photocatalytic hydrogen evolution

Dalton Transactions, ISSN: 1477-9234, Vol: 48, Issue: 8, Page: 2715-2721
2019
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Article Description

A new synthetic method was used to develop a CdS/MoS heterojunction. Cd-MOF was coated onto the surface of MoS flowers to construct a core-shell MoS @Cd-MOF. Thioacetamide was used as a sulfur source to sulfurize the MoS @Cd-MOF to form a CdS/MoS heterojunction. Since the Cd ions were highly ordered and separated by the organic ligands of the Cd-MOF shell, the as-synthesized CdS/MoS heterojunction possessed a large surface area and intimate contact at the heterogeneous interface with a uniform loading of CdS nanoparticles on the MoS flowers. Consequently, the CdS/MoS heterojunction exhibited a significantly enhanced photocatalytic H evolution rate of average 5587 μmol h g under UV-visible light irradiation.

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