IClick cycloaddition reaction of light-triggered manganese(i) carbonyl complexes
New Journal of Chemistry, ISSN: 1369-9261, Vol: 42, Issue: 22, Page: 18418-18425
2018
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Mono- and binuclear blue-light-induced CO-releasing molecules based on a fac-MnBr(CO) moiety and bearing benzimidazole ligands furnished with either a sulfonate or phosphonium group were synthesized. The effect of the ancillary ligand (Br and NCS) on the CO releasing properties was studied and compared with that of the triazolate complex synthesized by the free catalyst [3+2] cycloaddition iClick reaction. An extension of the iClick reaction to the binuclear complex was successful. The assignment of electronic transitions was done by TDDFT. The photoprocess of the binuclear complexes was faster than that of the mononuclear complex.
Bibliographic Details
Royal Society of Chemistry (RSC)
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