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One-step highly selective borylation/Suzuki cross-coupling of two distinct aryl bromides in pure water

New Journal of Chemistry, ISSN: 1369-9261, Vol: 42, Issue: 20, Page: 16464-16468
2018
  • 11
    Citations
  • 0
    Usage
  • 11
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    11
    • Citation Indexes
      11
  • Captures
    11

Article Description

A NaPdCl-catalysed B(OH)-mediated direct cross-coupling of two distinct aryl bromides in pure water is described. This one-step borylation/Suzuki method exhibits an outstanding cross-coupling selectivity and no tendency to produce homocoupling products, therefore leading to biaryls and heterobiaryls in moderate to good yields. Moreover, the reaction has high regio-selectivity and can be scaled-up. Using such a simple, economical and practical protocol, the unsymmetrical diarylation of 3,5-dibromopryidine is achieved.

Bibliographic Details

Xu, Shan Dong; Sun, Fang Zhou; Deng, Wei Hang; Hao, Han; Duan, Xin Hong

Royal Society of Chemistry (RSC)

Chemical Engineering; Chemistry; Materials Science

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