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An enantioselective synthesis of α-alkylated pyrroles: Via cooperative isothiourea/palladium catalysis

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 17, Issue: 7, Page: 1787-1790
2019
  • 32
    Citations
  • 0
    Usage
  • 14
    Captures
  • 0
    Mentions
  • 43
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    32
  • Captures
    14
  • Social Media
    43
    • Shares, Likes & Comments
      43
      • Facebook
        43

Article Description

Herein we describe the direct enantioselective Lewis base/Pd catalysed α-allylation of pyrrole acetic acid esters. This provides high isolated yields of highly enantioenriched products and exhibits broad reaction scope with respect to both reaction partners. The products can be readily elaborated in a manner which points towards potential applications in target directed synthesis.

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