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Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water

Journal of Materials Chemistry A, ISSN: 2050-7496, Vol: 6, Issue: 14, Page: 5608-5612
2018
  • 37
    Citations
  • 0
    Usage
  • 33
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    37
    • Citation Indexes
      37
  • Captures
    33

Article Description

Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g at 293 K, which surpassed that of adsorbent materials reported in the literature.

Bibliographic Details

Jin Xiu Zhou; Xian Sheng Luo; Xiangxiang Liu; Mu Hua Huang; Shi Lu Chen; Yan Qiao; Pengfei Wang; David Mecerreyes; Nicolas Bogliotti

Royal Society of Chemistry (RSC)

Chemistry; Energy; Materials Science

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