Azo-linked porous organic polymers: Robust and time-efficient synthesis: Via NaBH-mediated reductive homocoupling on polynitro monomers and adsorption capacity towards aniline in water
Journal of Materials Chemistry A, ISSN: 2050-7496, Vol: 6, Issue: 14, Page: 5608-5612
2018
- 37Citations
- 33Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials. In this work, we show a robust and time-efficient synthetic method of azo-linked porous organic polymers named Azo-POPs based on a NaBH-mediated reductive coupling polymerization on well-known polynitro monomers. Azo-POPs were found to have a high Brunauer-Emmett-Teller (BET) surface area and potential for aniline adsorption. Interestingly, Azo-POP-1 showed adsorption capacity towards aniline as high as 1059.68 mg g at 293 K, which surpassed that of adsorbent materials reported in the literature.
Bibliographic Details
Royal Society of Chemistry (RSC)
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