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Dihalogen-bridged NHC-palladium(i) dimers: Synthesis, characterisation and applications in cross-coupling reactions

Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 36, Page: 5275-5278
2019
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Article Description

A di-iodo-bridged Pd dimer bearing an N-heterocyclic carbene ligand was made accessible via the reduction of [(IPr)PdI] in basic methanol solution. The structural features of [(IPr)PdI] were explored by single-crystal X-ray analysis. It was found to be a convenient one-component precatalyst with high activity in Suzuki-Miyaura, Buchwald-Hartwig, and Sonogashira reactions.

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