Pentadienyl migration and abstraction in yttrium aluminabenzene complexes including a single-component catalyst for isoprene polymerization
Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 49, Page: 7089-7092
2019
- 16Citations
- 11Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations16
- Citation Indexes16
- 16
- CrossRef11
- Captures11
- Readers11
- 11
Article Description
Aluminabenzene complex [(1-Me-3,5-tBu-CHAl)(μ-Me)Y(2,4-dtbp)] (2,4-dtbp = 2,4-di-tert-butylpentadienyl) reacts with LiN(SiHMe) according to a methyl/silylamido exchange and formation of [(1-Me-3,5-tBu-CHAl){μ-N(SiHMe)}Ln(2,4-dtbp)] which engages in a donor(THF)-dependent reversible Ln-to-Al-pentadienyl migration. The reaction of [(1-Me-3,5-tBu-CHAl)(μ-Me)Y(2,4-dtbp)] with [CPh][B(CF)] results in pentadienyl group abstraction affording cationic complex [(1-Me-3,5-tBu-CHAl)(μ-Me)Y(benzene)][B(CF)] which acts as a single-component catalyst in isoprene polymerization.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85067281053&origin=inward; http://dx.doi.org/10.1039/c9cc02857a; http://www.ncbi.nlm.nih.gov/pubmed/31150028; https://xlink.rsc.org/?DOI=C9CC02857A; https://dx.doi.org/10.1039/c9cc02857a; https://pubs.rsc.org/en/content/articlelanding/2019/cc/c9cc02857a
Royal Society of Chemistry (RSC)
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