Transition metal-free hydrodefluorination of acid fluorides and organofluorines by PhGeH promoted by catalytic[PhC][B(CF)]
Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 73, Page: 10852-10855
2019
- 14Citations
- 17Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
It has been shown that the germane PhGeH converts aryl and aliphatic acid fluorides directly to their corresponding aldehydes without over-reduction via the conversion of PhGeH to the germylium cation[PhGe] by a catalytic amount of the tritylium salt[PhC][B(CF)]. Here, no transition metal catalyst is required and there is no decarbonylation of the acid fluoride, which are advantages over existing methods. The fluorine atoms can also be abstracted from organofluorine compounds using this method.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85071996474&origin=inward; http://dx.doi.org/10.1039/c9cc05075b; http://www.ncbi.nlm.nih.gov/pubmed/31453582; https://xlink.rsc.org/?DOI=C9CC05075B; https://dx.doi.org/10.1039/c9cc05075b; https://pubs.rsc.org/en/content/articlelanding/2019/cc/c9cc05075b
Royal Society of Chemistry (RSC)
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