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Transition metal-free hydrodefluorination of acid fluorides and organofluorines by PhGeH promoted by catalytic[PhC][B(CF)]

Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 73, Page: 10852-10855
2019
  • 14
    Citations
  • 0
    Usage
  • 17
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    14
    • Citation Indexes
      14
  • Captures
    17

Article Description

It has been shown that the germane PhGeH converts aryl and aliphatic acid fluorides directly to their corresponding aldehydes without over-reduction via the conversion of PhGeH to the germylium cation[PhGe] by a catalytic amount of the tritylium salt[PhC][B(CF)]. Here, no transition metal catalyst is required and there is no decarbonylation of the acid fluoride, which are advantages over existing methods. The fluorine atoms can also be abstracted from organofluorine compounds using this method.

Bibliographic Details

Hayatifar, Ardalan; Borrego, Alejandro; Bosek, David; Czarnecki, Matthew; Derocher, Gabriel; Kuplicki, Adam; Lytle, Erik; Padilla, Jonas; Paroly, Charles; Tubay, Gillian; Vyletel, Jackson; Weinert, Charles S

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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