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Chemically grafting nanoscale UIO-66 onto polypyrrole nanotubes for long-life lithium-sulfur batteries

Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 80, Page: 12108-12111
2019
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Article Description

A versatile strategy for a facile approach to chemical graft MOFs onto polypyrrole nanotubes (PPyNTs@MOFs) is designed and fabricated rationally by means of 1,4-dibromobutane linkage. Various MOFs arranged randomly close-packed on PPyNTs, including Co, Cu, Zn, Mn, Fe, Al, Ti, Cr, Zr and V, have been synthesized successfully. The as-prepared PPyNT@UIO-66 hybrids, used as a cathode carrier, exhibit excellent cyclic stability in Li-S batteries via strong physical and chemical adsorption/affinity with polysulfides.

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