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Ni(ii)-catalyzed mono-selective: Ortho -arylation of unactivated aryl C-H bonds utilizing amino acids as a directing group

RSC Advances, ISSN: 2046-2069, Vol: 9, Issue: 19, Page: 10820-10824
2019
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Article Description

The nickel(ii)-catalyzed ortho-arylation of unactivated C-H bonds utilizing amino acids as directing groups with aryl iodides or bromides as coupling electrophiles is described. This protocol features excellent mono-selectivity, good regioselectivity, and wide functional group tolerance. Additionally, the obtained products bearing a biaryl motif and an amino acid represent bioactive molecules with wide bioactivities.

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