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A flexible self-folding receptor for coronene

Chemical Science, ISSN: 2041-6539, Vol: 10, Issue: 44, Page: 10351-10355
2019
  • 12
    Citations
  • 0
    Usage
  • 13
    Captures
  • 0
    Mentions
  • 28
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    12
  • Captures
    13
  • Social Media
    28
    • Shares, Likes & Comments
      28
      • Facebook
        28

Article Description

We report a conformationally flexible deep cavitand receptor based on calix[5]arene and stabilized by a cooperative network of hydrogen bonds. The receptor binds coronene selectively over smaller polycyclic aromatic hydrocarbons, but is flexible enough to adapt to a smaller guest that presents a complementary electron deficient surface. The unique dynamic properties of this system have been thoroughly studied by NMR spectroscopy and molecular dynamics (MD) simulations.

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