A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair
Chemical Communications, ISSN: 1364-548X, Vol: 56, Issue: 62, Page: 8806-8809
2020
- 8Citations
- 14Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations8
- Citation Indexes8
- CrossRef7
- Captures14
- Readers14
- 14
Article Description
(2,6-Dimesitylphenyl)P(vinyl)25d reacts with HB(C6F5)2 in a sequence involving a rare example of a 1,1-carboboration of an olefin to give the borylated tetrahydrophosphole derivative 6d. Compound 6d is an active frustrated Lewis pair that splits dihydrogen under mild conditions and serves as a metal-free hydrogenation catalyst. It also adds to carbon dioxide. Compound 6d serves as an intermediate in the HB(C6F5)2 catalyzed aryl(divinyl)phosphane (5d) to dihydrophosphole conversion. This journal is
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85089163128&origin=inward; http://dx.doi.org/10.1039/d0cc01255f; http://www.ncbi.nlm.nih.gov/pubmed/32626861; https://xlink.rsc.org/?DOI=D0CC01255F; https://dx.doi.org/10.1039/d0cc01255f; https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc01255f
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know