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Unexpected persistence ofcis-bridged chains in compressed AuF

Chemical Communications, ISSN: 1364-548X, Vol: 56, Issue: 36, Page: 4902-4905
2020
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Article Description

Raman scattering measurements indicate thatcis-bridged chains are retained in AuFeven at a compression of 45 GPa - in contrast tometa-GGA calculations suggesting that structures with such motifs are thermodynamically unstable above 4 GPa. This metastability implies that novel gold fluorides (e.g.AuF) might be attainable at lower pressures than previously proposed.

Bibliographic Details

Kurzydłowski, Dominik; Kobyakov, Serhiy; Mazej, Zoran; Pillai, Sharad Babu; Chakraborty, Brahmananda; Jha, Prafulla K

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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