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Terbium-fluorido cluster: An energy cage for photoluminescence

Chemical Communications, ISSN: 1364-548X, Vol: 56, Issue: 64, Page: 9130-9133
2020
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Article Description

We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters. This journal is

Bibliographic Details

Ling, Bo-Kai; Li, Junhao; Zhai, Yuan-Qi; Hsu, Hung-Kai; Chan, Yi-Tsu; Chen, Wei-Peng; Han, Tian; Zheng, Yan-Zhen

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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