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Temporary (P=O) directing group enabled carbazoleorthoarylationviapalladium catalysis

Chemical Communications, ISSN: 1364-548X, Vol: 57, Issue: 16, Page: 2021-2024
2021
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Article Description

A palladium-catalyzed, temporary P(O) directing group assisted C-H bond arylation of carbazoles was achieved. The release of the directing group occurs spontaneously in the reaction and the mechanistic studies indicate that acid is essential for N-P bond cleavage.

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