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Porous noria polymer: a cage-to-network approach toward a robust catalyst for COfixation and nitroarene reduction

Chemical Communications, ISSN: 1364-548X, Vol: 57, Issue: 36, Page: 4404-4407
2021
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The advantages of the cage-to-network design strategy were demonstrated by knitting a waterwheel-like preporous molecular cage, noria, with a rigid aromatic linker to obtain a highly microporous organic polymer (NPOP,S: 748 ± 25 mg). The NPOP was employed for the catalytic conversion of COto cyclic carbonates under solvent-free reaction conditions. Furthermore, a silver nanoparticle encapsulated NPOP exhibited remarkable catalytic activity for nitroarene reduction with excellent recyclability.

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