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Carbon dioxide induced structural phase transition in metal-organic frameworks CPO-27

CrystEngComm, ISSN: 1466-8033, Vol: 22, Issue: 26, Page: 4353-4358
2020
  • 6
    Citations
  • 0
    Usage
  • 9
    Captures
  • 0
    Mentions
  • 1
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    6
    • Citation Indexes
      6
  • Captures
    9
  • Social Media
    1
    • Shares, Likes & Comments
      1
      • Facebook
        1

Article Description

A phase transition occurs in metal-organic framework CPO-27-M (M = Co and Zn) below ∼110 K in CO2 atmosphere. The phase change involves the collective rearrangement of the inorganic chains and the organic ligands of the honeycomb framework. The new phase represents a superstructure of the original unit cell with doubled a and b axes, in which the cylindrical pore of the original phase transforms into two different pores.

Bibliographic Details

Breogán Pato-Doldán; Mali H. Rosnes; Dmitry Chernyshov; Pascal D. C. Dietzel

Royal Society of Chemistry (RSC)

Chemistry; Materials Science; Physics and Astronomy

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