Activation of hydrogen peroxide by the nitrate anion in micellar media
Green Chemistry, ISSN: 1463-9270, Vol: 23, Issue: 5, Page: 1965-1971
2021
- 4Citations
- 8Captures
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Article Description
We present the activation of hydrogen peroxide by micellar imidazolium nitratesviaH-bond formation in water, as shown by vibrational spectroscopy and supported by DFT calculations. Mechanistic insight into the interactions of the surfactant cation, the nitrate anion and HOis given. The micelles solubilise and epoxidise cyclooctene in the aqueous phase.
Bibliographic Details
Royal Society of Chemistry (RSC)
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