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Activation of hydrogen peroxide by the nitrate anion in micellar media

Green Chemistry, ISSN: 1463-9270, Vol: 23, Issue: 5, Page: 1965-1971
2021
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Article Description

We present the activation of hydrogen peroxide by micellar imidazolium nitratesviaH-bond formation in water, as shown by vibrational spectroscopy and supported by DFT calculations. Mechanistic insight into the interactions of the surfactant cation, the nitrate anion and HOis given. The micelles solubilise and epoxidise cyclooctene in the aqueous phase.

Bibliographic Details

Fabian Schmidt; Marlene Kaposi; Markus Drees; Mirza Cokoja; Bastian Zehner; Wolfgang Korth; Andreas Jess; János Mink

Royal Society of Chemistry (RSC)

Environmental Science

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